It seems very common (particularly among non-native English speakers, but I've seen the typed form, though not the spoken form, from native speakers too) for people to type or even say "substraction" when they mean "subtraction".
What causes this error? There must be some loose rule that the word "subtract" fails to follow, to cause the -s- to be inserted so commonly. Is it a phonotactics thing?
I'm not sure if this is the best place to ask this; it's possible that english.SE would be a better place for this. Feel free to move it if so.